Dr Anil K Suresh is a renowned scientist in the area of Bio-Nanotechnology . The prestigious Ramalingaswami Fellow is now an Associate Professor at the Department of Biological Sciences, SRM University-AP. He recently developed an innovative catalyst that he named “Jumbo Catalyst” to address the demanding challenges in heterogeneous catalysis. This 3D-megacatalyst generated using “intact eggshell” food-waste is hand-removable with an overall surface area of ~ 78 cm2, featuring wide catalytic support and is highly stable in polar and non-polar solvents for ultra-efficient heterogeneous catalysis. This megacatalyst can overcome the existing limitations such as cost, time, labour, sustainability, mechanical stability, diverse-reactions, large-volumes, aggregation, recyclability and precursor recovery. Dr Anil K Suresh owns the copyrights for this pathbreaking invention through a published patent.

Catalysis is widely used in various industrial processes to produce desired end products. Research in this area substantially evolved from using organic reagents and metals to the adaptation of metal-based nanoparticles. Supported catalysis is a fast-emerging class of catalysis using inert and supportive frameworks with a potential for efficient reuse and recovery of the catalyst. Synthesis of metal-organic frameworks, fibres, polymers and hydrogel-based catalytic nanoparticle loadings are being reported. However, these are associated with intrinsic complexities and are produced using toxic ingredients, ecologically unbenign and are expensive.

The megacatalyst, generated by Dr Anil and his team using eggshell food-waste in the process, is autogenic, facile, cost-efficient and entirely biodegradable. Dr Anil strongly believes that theirs is the biggest catalyst developed so far. The intact eggshell provides an extensive support area for ultra-efficient catalysis. Applicability of this megacatalyst is so simple that even a layman can use it with ease. Moreover, this supported megacatalyst can be effortlessly removed from the reaction mixture post application as it can be recovered by hand. Catalytic reactions using the megacatalyst can be controlled as the tuff, and uniform coating protects the shedding of nanoparticles. Dr Anil Says, “We presume that the mega-size of the catalyst could be instrumental in several challenging applications. As a proof of concept, we selected three eclectic applications including- 1. Large volume sewage dye degradations, 2. Gram-scale hydrogenation of nitroarenes and 3. Transesterification of used oil to biodiesel- which are all difficult to achieve, highly challenging but are now practically feasible using our megacatalyst.”

“Keeping in mind the ultra-catalytic proficiency of our catalyst that can be simply resourced from continuously available eggshell waste, with minimal maintenance for the large scale practical implementation, we welcome interested beneficiaries from diverse heterogeneous catalysis sectors for bringing this innovation to execution,” Dr Anil asserted.

The team is currently investigating to design and fabricate other species of megacatalyst using other significant metal precursors and earth-abundant metals to expand the applicability in allowance of diverse reactions such as oxidation of CO, Methane, Mono/Polyhydric alcohols, hydrogenation of alkynes, Nitroaromatics and CO2.
Dr Anil K. Suresh concluded that this breakthrough conception would not have been possible without the rigorous efforts of his team and the continuous support from the university management. Dr Anil Suresh thanked his PhD students Chandra Bhatt, Divya Parimi, Tharun Bollu and Madhura. Dr Anil especially thanked Professor D Narayana Rao, Pro-Vice-Chancellor, SRM University-AP for his extensive support in all his scientific endeavours since his association with the university.

Converting waste to fuel: way forward to a resilient planet

Dr Lakhveer Singh, Assistant Professor, Department of Environmental Science published a book titled “Waste to Sustainable Energy: MFCs – Prospects through Prognosis”. This book has been featured in the list of Best Waste Management books of all time by CNN, Forbes, and Inc-Book Authority. The book has been awarded this stature by venerated reviewers of the International Expert Committee, as well as global leaders of the discipline.

A Microbial Fuel Cells (MFC) bio-refinery treat water using microorganisms and converts waste products and byproducts into fuel. This entails efficient waste management along with contributing to the generation of renewable fuel, and products that foster sustainable development. Addressing the present challenges in waste management, bioenergy, bioproduct recovery, and commercial sustainability, this book on MFCs emphasize on an array of mechanisms, routes, and reaction engineering approaches for extensive transformation of waste to wealth.

Extensive use of fossil fuels for energy emits carbon dioxide and other harmful gases adversely affecting the environment and leading to soaring global warming. Subsequently, domestic, agricultural waste products from animal facilities, refineries, and industries cause a tremendous environmental burden. Energy systems from MFCs enable the treatment and recycling of wastes, preventing environmental problems, and offsetting the pollution loads. Dr Lakhveer informs, “We are aiming at ensuring a sustainable and resilient environment that eliminates any potential odds of future climate change. Though globalization has preceded the escalation in production processes, a significant quantum of the waste materials generated through these practices can be transformed into fuels with the help of MFCs. Efficacies of this mechanism would ensure a paradigm shift built on the principles of sustainability.”

This book focuses on the MFCs with various combinations of substrates generating bioelectricity with valued co-products. Essentially, the book provides fundamental ideas on MFC technologies, entailing various design and modeling aspects with examples. Further, the book illustrates distinctive aspects of basic sciences, reactor configuration, application, and market feasibility of MFCs. Critically assessing the feasibility of waste-powered MFCs for sustainable bioenergy production, the book highlights the tradeoff between resource needs and energy production. The extensive research and details in the book will help academicians, entrepreneurs, and industrialists to understand the scope and challenges empowering them to select unique, and specific integrated approaches in unit processes.

Advancing his research to mitigate environmental issues, Dr Lakhveer will continue to explore bioenergy, water treatment, bioelectrochemical systems, and nanomaterial synthesis for energy and water applications, and bioreactors development. Also, he is presently editing two books that address several environmental challenges.

Dr Nimai Mishra, Assistant Professor, Department of Chemistry, SRM University-AP, Andhra Pradesh, accompanied by his research group encompassing students pursuing PhD under him, Mr. Syed Akhil and Ms. V.G.Vasavi Dutt have published a comprehensive mini-review titled “Amine-Free Synthesis of Colloidal Cesium Lead Halide Perovskite Nanocrystals” in the Journal “ChemNanoMat” (Wiley-VCH) with an Impact Factor of 3.4.

Colloidal cesium lead halide (CsPbX₃) perovskite nanocrystals (PNCs) are emerging disciplines in research aided by their exceptional optical properties and remarkable colour tunability. Oleic acid and oleylamine are the frequently used surface capping ligands in colloidal CsPbX3 synthesis. The oleylamine plays an important role in surface passivation and maintaining colloidal stability. However, in the long run, it is accountable for poor colloidal stability because of the facile proton exchange. This heralds to the formation of labile oleylammonium halide, which removes the halide ions from the Nanocrystals’ surface.

Leveraging on the synthetic toolboxes developed from decades of research into more traditional semiconductor nanocrystals, lately, researchers are focusing on creating various amine‐free synthesis approaches to improve the colloidal and photostability of CsPbX₃ perovskite NCs. In this paper, Dr Mishra and his team encapsulated various amine‐free based synthetic routes of CsPbX₃ (X=Cl, Br, I) PNCs that have been reported so far. They reviewed this progress in terms of their underlying synthetic approaches, and post‐synthetic treatment steps.

Furthermore, Dr Mishra and his group analyzed the prospects of these perovskite nanocrystals in terms of their photo‐luminescence properties and device performances. Advancing, a deeper understanding of the role of precursors and ligands will significantly bolster the versatility of these amine‐free PNC materials.

To read the full paper: Please Click Here

Prof C Durga Rao (Principal Investigator), Professor, Department of Biological Sciences, and Associate Dean, Sciences, Department of Biological Sciences, SRM University-AP, Andhra Pradesh has received a total outlay of Rs. 1,10,52,941/- from the Department of Biotechnology, Government of India, to work on the project titled “Understanding the molecular basis for the extreme differential level of expression of genes from human and animal rotaviruses in gene-transfected cells: Implications for improving the growth of human vaccine strains”. Using the grant, the professor will be spawning the appropriate facilities to perform cell culture and virus-related research at SRM University-AP.

Understanding how a virus overpowers the host resistance mechanisms and seizes the host cellular processes for its own growth is very challenging and is essential for the development of not only efficient viral vaccines but also for antiviral therapeutic strategies. Prof Durga Rao informs, “Rotavirus is the leading cause of severe and acute dehydrating diarrhoea in infants and children below 5 years of age. Efforts by us and Dr Bhan, former Secretary, Department of Biotechnology, Government of India, led to the discovery and development of the first made in India rotavirus vaccine, produced by Bharat Biotech, Hyderabad.”

In the earlier project, the professor Rao observed that while some human rotaviral proteins could be expressed at high levels when the cloned genes were introduced into mammalian cells, other proteins could not be expressed at detectable levels. However, the virus expresses copious amounts of all its proteins when it infects the cells. Prof Durga Rao further shares, “Within a few hours of infection, each virus employs several ploys in the infected cell to subvert the cellular defence and regulatory mechanisms and captures the host for its own progeny production.”

Based on the earlier observations, this project will advance to unravel the tricks employed by the virus, and viral transactions in the infected cells. The outcome of the project will have implications for genetically engineering the poorly growing human vaccine strains for their efficient growth in cell culture, leading to reduced cost of not only rotavirus vaccines, but also other viral vaccines.

Prof Ranjit Thapa, Professor, Department of Physics, SRM University – AP, Andhra Pradesh has been awarded a first-year grant of Rs 28 Lakhs by the National Supercomputing Mission (NSM), supported by the Department of Science and Technology (DST) in collaboration with the Ministry of Electronics and Information Technology (MeITy), Government of India. Prof Ranjit will be working on the project titled “Catalysts for CO2 Reduction to C2 Product: Descriptor to Database” as the project leader. He has started the work to search for the best catalyst to convert CO2 into useful product and hence solving the problem of climate change due to large production of CO2 through different sources.

CO2 is a known greenhouse gas and key reason for global warming and climate change. Can we challenge mother nature by converting CO2, a greenhouse gas into energy with the required efficiency? This is a mystery and a mammoth problem and a much-needed problem to be solved with a fundamental approach. Prof Ranjit Thapa believes that metal nanocatalyst on support materials can solve the problem and can increase the efficiency of CO2 reduction to C2 products, viz., ethylene (C2H4) and ethanol (C2H5OH). An experimental approach to find the best catalyst for CO2 reduction needs enormous funds and trials, and a long time is required to develop the exact catalyst for industry application. The mammoth task is to find the suitable composition, shape, and size of metal nanoparticle (MNP) on an appropriate surface for the catalytic reactions. Prof. Ranjit proposes that this can be achieved by computational modelling using Density Functional Theory (DFT) through finding and estimating the electronic descriptor and revealing active sites through structure-activity relations. Recent progress in Machine Learning (ML) for materials with DFT modelling drives towards rational design of catalysts. The electronic descriptor, storage of MNP/support information in the database followed by prediction using Machine Learning (using predictive model equation) will help to narrow down the search for the best catalyst for CO2 reduction to C2 species.

Further, Dr Mahesh Kumar Ravva, Assistant Professor, Department of Chemistry, SRM University – AP, Andhra Pradesh received Rs 19.92 Lakhs as the first instalment from DST-National Supercomputing Mission (NSM). His project’s primary focus will be on understanding the critical factors that influence the performance of organic solar cells. Using the supercomputer, his research group will model the electronic process that occurs during solar cell operation. The outcome of this project will guide experimentalists to develop organic solar cells with higher efficiency. Organic solar cells are flexible, lightweight, and low-cost and have many exciting applications in wearable electronic devices, smart windows, etc.

Prof V S Rao, Vice-Chancellor, SRM University – AP, and Prof D Narayana Rao, Pro Vice-Chancellor, SRM University – AP congratulated Prof Ranjit Thapa and Dr Mahesh Kumar Ravva. Prof Narayana Rao said, “Necessary facilities and support will be provided by the University to effectively carry out the two projects.”